13C–13C spin-coupling constants in crystalline 13C-labeled saccharides: conformational effects interrogated by solid-state 13C NMR spectroscopy

Zhang, W.; Yoon, M. K.; Meredith, R.J.; Zajicek, J.; Hadad, M. J.; Oliver, A.G.; Frey, M.H.; Carmichael, I.; Serianni, A. S.

doi:10.1039/c9cp03228b

13C–13C spin-coupling constants in crystalline 13C-labeled saccharides: conformational effects interrogated by solid-state 13C NMR spectroscopy

journal contribution

posted on 2024-11-07, 20:01 authored by W. Zhang, M. K. Yoon, R.J. Meredith, J. Zajicek, M. J. Hadad, A.G. Oliver, M.H. Frey, I. Carmichael, A. S. Serianni

Solid-state ¹³C NMR reveals differences in O-glycosidic linkage conformation in solution and in crystalline disaccharides. Experimental J_CC values in crystalline samples provide a means of validating J_CC calculated from density functional theory.

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2019

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Page 23576

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Phys. Chem. Chem. Phys.

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Volume 21

13C–13C spin-coupling constants in crystalline 13C-labeled saccharides: conformational effects interrogated by solid-state 13C NMR spectroscopy

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