Supramolecular receptor design: Anion-triggered binding of C60
journal contribution
posted on 2024-11-07, 19:52 authored by K. A. Nielsen, W. S. Cho, G. H. Sarova, B. M. Petersen, A. D. Bond, J. Becher, F. Jensen, D. M. Guldi, J. L. Sessler, J. O. JeppesenSeeing is believing: Treatment of a tetrathiafulvalene-functionalized calix[4]pyrrole 1 with chloride anions in CH2Cl2 produces bowl-like receptor 1⋅Cl−, which is able to encapsulate C60 in a 2:1 barrel-like manner. The color of C60⊂(1⋅Cl−)2 (green in CH2Cl2) differs dramatically from its constituents (yellow and magenta for 1 and C60, respectively), thus allowing its formation to be monitored visually.
Funding
Lundbeckfonden, The Strategic Research Coouncil in Denmark, Young Researchers Program, Danish Natural Science Research Council, European Science Foundation, European Commission, Danish Center for Scientific Computing. Deutsche Forschungsgemeinschaft
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2006Extent
Page 6848-53Publisher
Angew. Chem. Int. Ed.Source
Volume 45Usage metrics
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