posted on 2012-08-16, 00:00authored bySarrah Marie Dunham-Cheatham
<p>The research conducted in these chapters focused on the transport and fate of a range of metals in the presence of bacteria. In Chapter 2, I investigated the effects of bacteria on the precipitation of metal phosphates and discovered 2 phenomena, passive cell wall mineralization and the decreased size of precipitated minerals due to the presence of bacteria. In Chapters 3 and 4, I investigated the effects of 2 ligands (chloride in Chapter 3, fulvic acid in Chapter 4) on the adsorption behavior on mercury to bacterial cells. I learned from these studies that the presence of ligands can have a range of effects on the adsorption behavior of mercury to bacterial cells.</p> <p>In all of my investigations, I used thermodynamic models to calculate stability constants for several metal-bacteria complexes formed in my experiments. These stability constants can be used to better predict the behavior of metals in metal-bacteria-ligand systems, which is potentially beneficial to several applications (e.g. developing effective remediation strategies).</p>
History
Publisher
University of Notre Dame
Date Modified
2017-06-02
Language
English
Additional Groups
Civil and Environmental Engineering and Earth Sciences
Alternate Identifier
etd-08162012-214616
Defense Date
2012-07-27
Research Director(s)
Jeremy Fein
Committee Members
Robert Nerenberg
Joshua Shrout
Patricia Maurice
Degree
Doctor of Philosophy
Degree Level
Doctoral Dissertation
Program Name
Civil and Environmental Engineering and Earth Sciences