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  Article

  Identifying the True Catalyst in the Reduction of 4-Nitrophenol: A Case Study Showing the Effect of Leaching and Oxidative Etching Using Ag Catalysts
  

  Author(s):

  Eredzhep Menumerov, Robert Hughes, Spencer Golze, Robert Neal, Trevor Demille, Justin Campanaro, Kyle Kotecky, Sergei Rouvimov, Svetlana Neretina

  Abstract:

  The fundamental understanding of liquid-phase catalytic reactions is unavoidably complicated when the catalyst is prone to leaching since questions inevitably arise as to the true nature of the catalyst. While the catalytic reduction of 4-nitrophenol by borohydride is widely accepted as a trusted model reaction, it has faced little scrutiny concerning the potential impact of leached species or the appropriateness of assigning catalytic activity to the inserted nanostructures without rigorous …

  Date Published:

  2018

  Record Visibility:

  Public