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  Article

  Mechanisms of Self-Sustained Reaction in Mechanically Induced nanocomposites: Titanium Nitride and Boron
  

  Author(s):

  J. M. Pauls, N. F. Shkodich, A. S. Mukasyan

  Abstract:

  We report the results from the investigation of the mechanisms of self-sustained reaction in mechanically induced TiN/B nanocomposites. The exothermic displacement reaction, 3B + TiN → BN + TiB2, with an adiabatic reaction temperature of 1905 K, was initiated through two different means: localized thermal heating and mechanical stimulation by high-energy ball milling. Comprehensive studies strongly indicate that the chemical interaction in the system involves three main stages. Solid-state ma…

  Date Published:

  2019-04

  Record Visibility:

  Public