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- Author(s):
- Tor Elmelund, Rebecca Scheidt, Brian Seger, Prashant Kamat
- Abstract:
MAPbBr3 and MAPbI3 films cast onto glass slides and physically paired together undergo halide exchange to form mixed halide films. The change in halide composition in these two ∼130 nm thick films occurs concurrently with Br− diffusing toward the MAPbI3 film and I− diffusing toward the MAPbBr3 film. The diffusion of these halide species, which is tracked through changes in the absorption, offers a direct measurement of thermally activated halide diffusion in perovskite films. The increase in …
- Date Published:
- 2019-06
- Record Visibility:
- Public
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- Author(s):
- Rebecca Scheidt, Corey Atwell, Prashant Kamat
- Abstract:
The control of grain size and surface properties is an important parameter in controlling the optoelectronic and photovoltaic properties of metal halide perovskites. When CsPbBr 3 nanocrystal (∼10 nm in diameter) films were annealed at 100−125 °C, they grow in size to produce ∼400 nm diameter crystallites while transforming into bulk perovskite films. Characteristic changes in the optical properties were noted when such transformation occurred from nanocrystals into bulk. By tracking absorban…
- Date Published:
- 2019-06
- Record Visibility:
- Public