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  • Author(s):
    Patrick Barboun, Prateek Mehta, Francisco Herrera, David Go, William Schneider, Jason Hicks
    Abstract:

    Plasma-assisted catalysis is the process of electrically activating gases in the plasma-phase at low temperatures and ambient pressure to drive reactions on catalyst surfaces. Plasma-assisted catalytic processes combine conventional heterogeneous surface reactions, homogeneous plasma phase reactions, and coupling between plasma-generated species and the catalyst surface. Herein, we perform kinetically controlled ammonia synthesis measurements in a dielectric barrier discharge (DBD) plasma-ass…

    Date Published:
    2019-07
  • Author(s):
    A. M. Mintairov, D. V. Lebedev, N. Bert, K. G. Belyaev, V. N. Nevedomskiy, M. V. Rakhlin, A. A. Toropov, A. S. Vlasov, A. Gocalinska, G. Juska, E. Pelucchi, M. A. Arrendondo, A. B. Naden, A. V. Shelaev, V. A. Bykov
    Abstract:

    We used transmission electron microscopy, Raman, and photoluminescence spectroscopy to identify the effect of CuPt-type GaP-InP atomic ordering (AO) on the structural and emission properties of self-organized (SO) InP/GaInP2 Wigner molecule (WM) quantum dot (QD) structures. We found that the correlation of AO and SO growth results in the formation of InP/GaInP2 QD/AO-domain (QD/AOD) core-shell composites. This observation shows that intrinsic WMs in this system emerge due to a strong piezoele…

    Date Published:
    2019-11
  • Author(s):
    Junsang Cho, Jeffrey T. DuBose, Prashant Kamat
    Abstract:

    Lead-free double perovskites such as Cs2AgBiBr6 are gaining attention because of their environmental friendliness compared to the lead halide perovskites. In order to establish their photoactivity, we have probed the excited-state behavior of Cs2AgBiBr6 nanocrystals and charge injection from their excited state into different metal oxides (TiO2, ZnO). The electron-transfer rate constants determined from ultrafast transient absorption spectroscopy were in the range of 1.2−5.2 × 1010 s−1. Under…

    Date Published:
    2019-12
  • Author(s):
    Margo Waters, Veronica Kalwajtys, Katelyn Carothers, Ryan Roeder, Joshua Shrout, Shaun Lee, Prakash Nallathamby
    Abstract:

    The increasing frequency of nosocomial infections caused by antibiotic-resistant microorganisms concurrent with the stagnant discovery of new classes of antibiotics has made the development of new antibacterial agents a critical priority. Our approach is an antibiotic-free strategy drawing inspiration from bacteriophages to combat antibiotic-resistant bacteria. We developed a nanoparticle-based antibacterial system that structurally mimics the protein-turret distribution on the head structure…

    Date Published:
    2019-10
  • Author(s):
    Wenzheng Kuang, Nicholas Kempf, Mortaza Saeidi-Javash, David Singh, Yanliang Zhang
    Abstract:

    Solution-processable semiconducting 2D nanoplates and 1D nanorods are attractive building blocks for diverse technologies, including thermoelectrics, optoelectronics, and electronics. However, transforming colloidal nanoparticles into high-performance and flexible devices remains a challenge. For example, flexible films prepared by solution-processed semiconducting nanocrystals are typically plagued by poor thermoelectric and electrical transport properties. Here, a highly scalable 3D conform…

    Date Published:
    2019-10
  • Author(s):
    Sachwa Chong, Sergei M. Aksenov, Frabrice Dal Bo, Samuel N. Perry, Foteini Dimakopoulou, Peter C. Burns
    Abstract:

    Uranyl vanadate compounds with divalent cations, M(UO2)(V2O7) (M = Ca, Sr) and Sr3(UO2)(V2O7)2, were synthesized by flux crystal growth, and their crystal structures were solved using single-crystal X-ray diffraction data. Ca(UO2)V2O7 and Sr(UO2)V2O7 were synthesized from reactants with molar ratios M:U:V of 1:1:2 and identical heating conditions, and increasing the M:U:V ratio to 3:1:4 resulted in Sr3(UO2)(V2O7)2. Crystallographic data for M(UO2)V2O7 compounds are: a = 7.1774(18) Å, b = 6.77…

    Date Published:
    2019-07
  • Author(s):
    Karen Torosyan, Alexey Sedegov, Kirill Kuskov, Mohammad Abedi, Dmitry Arkhipov, Philipp Kiryukhamtsev-Korneer, Stepan Vorotilo, Dmitry Moskovskikh
    Abstract:

    The influence of different SPS-based methods, that is, conventional spark plasma sintering (SPS), flash SPS (FSPS), and reactive SPS (RSPS) on the properties of Al2O3/SiC composite was investigated. It was shown that the application of preliminary high energy ball milling of the powders significantly enhances the sinterability of the ceramics. It was also demonstrated that FSPS provides unique conditions for rapid, that is, less than a minute, consolidation of refractory ceramics. The Al2O3-2…

    Date Published:
    2019-07
  • Author(s):
    Angela Meola, Nicole Hondroglannis, Pierce Brown, Maksym Zhukovskyi, Zheng Zheng, Zeev Rosenzweig, Mary Sajini Devadas
    Abstract:

    Icosahedron and [Au25(PPh)10(C6H14S)5Cl2]2+ bi-icosahedron clusters were synthesized. Ligand exchange reactions were carried out with a new coumarin-derived fluorophore (Cou-SH) to label both clusters. Labeled and unlabeled Au25 were compared and the changes in the electronic structure were determined. The labeled clusters showed marked changes in electronic states, as evidenced by the quenching in the UV region and enhancement in the near infrared. The quantum yield from Cou-SH decreased and…

    Date Published:
    2019-08
  • Author(s):
    Michael Hildreth, Natalie Meyers
    Abstract:

    The FAIR Hackathon Workshop for Mathematics and the Physical Sciences (MPS) February 27-28, 2019 in Alexandria, Virginia brought together forty-four stakeholders in the physical sciences community to share skills, tools and techniques to FAIRify research data. As one of the first efforts of its kind in the US, the workshop offered participants a way to engage with FAIR principles (Findable, Accessible, Interoperable and Reusable) Data and metrics in the context of a hackathon. The workshop wa…

    Date Created:
    2020-01-05
    Resource Type
    Report
  • Author(s):
    University of Notre Dame Hesburgh Libraries
    Abstract:

    The Pot of Gold Library Research and Information Literacy tutorial was designed to help students discover, assess, and use information in their coursework. It was built using PHP and JavaScript, and originally included Flash elements. The tutorial launched in the Fall of 2011 and will be retired from the Web in May 2020. The tutorial content was based on the [Begin Your Research tutorial](https://web.archive.org/web/20170830005738/http://www.lib.uci.edu/sites/all/tutorials/BeginResearch/publi

    Date Created:
    2011-08-01
    Resource Type
    Open Course Ware
  • Author(s):
    Anna McDermott, Samuel Herberg, Devon Mason, Joseph Collins, Hope Pearson, James Dawahare, Rui Tang, Amit N. Patwa, Mark Grinstaff, Daniel Kelly, Even Alsberg, Joel Boerckel
    Abstract:

    Large bone defects cannot form a callus and exhibit high complication rates even with the best treatment strategies available. Tissue engineering approaches often use scaffolds designed to match the properties of mature bone. However, natural fracture healing is most efficient when it recapitulates development, forming bone via a cartilage intermediate (endochondral ossification). Because mechanical forces are critical for proper endochondral bone development and fracture repair, we hypothesi…

    Date Published:
    2019-06
  • Author(s):
    Cheri Smith
    Abstract:

    In recent years, the Hesburgh Libraries at the University of Notre Dame have developed and sustained a partnership with our campus student wellness center (The McDonald Center for Student Well-Being - aka “McWell”) that includes several programs designed to promote overall physical, mental and emotional health for our users and our library staff. Our partnership began in 2016 with the introduction of McWell’s “Let’s Talk” service (https://ucc.nd.edu/lets-talk/), which is a program d…

    Date Created:
    2019-12-18
    Resource Type
    Presentation