Layer-by-layer modification of aliphatic polyamide anion-exchange membranes to increase Cl−/SO4 2− selectivity Muhammad

Article

Abstract

Development of anion-exchange membranes (AEMs) with selectivities among anions may expand the applications of these membranes in salt separations. This work shows that layer-by-layer coating of aliphatic polyamide AEMs with poly(4-styrenesulfonate) (PSS)/protonated poly(allylamine) (PAH) films enhances Cl − /SO 42− dialysis selectivities, and the extent of this enhancement depends on the source-phase salt concentrations. For a source phase containing 0.01 M NaCl and 0.01 M Na 2 SO 4 and a receiving phase of 0.01 M Na 2 CO 3 , a (PSS/PAH) 5 PSS coating (5 PSS/PAH “bilayers” capped with a layer of PSS) increases the Cl − /SO 42− selectivity from 1.7 to 5.3 in diffusion dialysis and from 1.3 to 7.4 in electrodialysis. Remarkably, the diffusion dialysis selectivity of a coated membrane increases to 140 when the salt concentrations in the source phase are 0.1 M. Even with bare membranes, selectivity increases to 13 with 0.1 M source-phase salt concentrations. Moreover, AEMs coated only on the receiving side show much higher selectivities but lower fluxes than those coated only on the source side. Partitioning experiments and modelling suggest that the increased Cl − /SO 42− selectivities at high source-phase salt concentrations stem from enhanced Cl − partitioning and electromigration that disproportionately decreases SO 42− flux in the AEM.

Attributes

Attribute NameValues
Creator
  • Muhammad Ahmad

  • Chao Tang

  • Liu Yang

  • Andriy Yaroshchuk

  • Merlin Bruening

Journal or Work Title
  • Journal of Membrane Science

Volume
  • 578

Issue
  • February

First Page
  • 209

Last Page
  • 219

ISSN
  • 18733123

Publication Date
  • 2019-02

Subject
  • Magellan SEM

Publisher
  • Elsevier

Date Created
  • 2020-02-18

Language
  • English

Departments and Units
Record Visibility Public
Content License
  • All rights reserved

Digital Object Identifier

doi:10.1016/j.memsci.2019.02.018

This DOI is the best way to cite this article.