Kinetics and Mechanism of Ignition in Reactive Al/Ni Nanostructured Materials

Article

Abstract

A high-speed electrothermography approach is applied to investigate the mechanism and kinetics for nanostructured Al/Ni foils. Application of the Kolmogorov-Johnson-Mehl-Avrami and adiabatic thermal explosion models reveal that the activation energy for nucleation appears to be much higher than that for reaction. It is shown that formation of intermetallic nuclei is the limiting step that defines the ignition characteristics of the foils at temperatures below 500 K, while the process is reaction limited at higher temperatures. Nucleation is also shown to play an important role during rapid (~10 m/s) propagation of the combustion (reaction) wave along the Al/Ni foils. These findings suggest new approaches for controlling the ignition and combustion processes for nanostructured reactive materials.

Attributes

Attribute NameValues
Creator
  • K. Manukyan

  • J. Pauls

  • C. Shuck

  • S. Rouvimov

  • A. Mukasyan

  • K. Nazaretyan

  • H. Chatilyan

  • S. Kharatyan

Journal or Work Title
  • The Journal of Physical Chemistry C: Physical Process in Nanomaterials and Nanostructures

Volume
  • 122

First Page
  • 27082

Last Page
  • 27092

ISSN
  • 1932-7447

ISBN
  • 157631608

Publication Date
  • 2018

Publisher
  • American Chemical Society

Date Created
  • 2018-12-07

Language
  • English

Departments and Units
Record Visibility Public
Content License
  • All rights reserved

Digital Object Identifier

doi:10.1021/acs.jpcc.8b09075

This DOI is the best way to cite this article.